Abstract

Previous abstract Back to issue content Next abstract
Symmetry: Culture and Science
Volume 31, Number 4, pages 439-447 (2020)
https://doi.org/10.26830/symmetry_2020_4_439

EXTREME ASYMMETRY AND CHIRALITY A CHALLENGING QUANTIFICATION

Michel Petitjean*

* Université de Paris, BFA, CNRS UMR 8251, INSERM ERL U1133, F-75013 Paris, France.
E-pôle de Génoinformatique, CNRS UMR 7592, Institut Jacques Monod, 75013 Paris, France.
E-mail: petitjean.chiral@gmail.com, michel.petitjean@univ-paris-diderot.fr
Web: http://petitjeanmichel.free.fr/itoweb.petitjean.html
ORCID: 0000-0002-1745-5402.

Abstract: Symmetry operators must be defined relatively to a space and to a metric. Complex symmetries are typically considered in the case of the cartesian product of the Euclidean space by a space whose elements are tuples of colors. While interesting open problems exist in this field, challenging ones remain in the Euclidean case, without invoking colors. We present some of these problems in the case of extreme chirality figures and of extreme asymmetrical probability distributions.

Keywords: chirality, mirror symmetry, asymmetry, skewness.
MSC 2020: 51M16, 52A40, 60E15

References:
Bouissou, C., Petitjean, M. (2018) Asymmetric Exchanges, J. Interd. Method. Iss. Sci., 4, 1–18, https://hal.archives-ouvertes.fr/hal-01782438.

Coppersmith, D., Petitjean, M. (2005) About the Optimal Density Associated to the Chiral Index of a Sample from a Bivariate Distribution, Compt. Rend. Acad. Sci. Paris, Sér. I, 340(8), 599–604, https://doi.org/10.1016/j.crma.2005.03.011.

Deza, M.M., Deza,E. (2009) Encyclopedia of Distances, Springer, Berlin, https://doi.org/10.1007/978-3-642-00234-2.

Dobrushin, R.L. (1970) Prescribing a system of random variables by conditional distributions, Theor. Prob. Appl. 15(3), 458–486, https://doi.org/10.1137/1115049.

Hestenes, D., Sobczyk, G. (1987) Clifford Algebra to Geometric Calculus, A Unified Language for Mathematics and Physics, section 3.8, D. Reidel Publising Co, Dordreht, The Netherlands, https://doi.org/10.1007/978-94-009-6292-7.

Lord Kelvin (1894) The Molecular Tactics of a Crystal, sect. 22, footnote p. 27, Clarendon Press, Oxford, UK, https://archive.org/details/moleculartactics00kelviala.

Lord Kelvin (1904) Baltimore Lectures on Molecular Dynamics and the Wave Theory of Light, appendix H, sect. 22, footnote p. 619, C.J. Clay and Sons, Cambridge University Press Warehouse, London, UK, https://archive.org/details/baltimorelecture00kelviala.

Petitjean, M. (1997) About Second Kind Continuous Chirality Measures. 1. Planar Sets, J. Math. Chem., 22(2-4), 185–201, https://doi.org/10.1023/A:1019132116175.

Petitjean, M. (1999a) Calcul de chiralité quantitative par la méthode des moindres carrés (in French), Compt. Rend. Acad. Sci. Paris, Sér. IIc, 2(1), 25–28, https://doi.org/10.1016/S1387-1609(99)80034-6.

Petitjean, M. (1999b) On the Root Mean Square Quantitative Chirality and Quantitative Symmetry Measures, J. Math. Phys., 40(9), 4587–4595, https://doi.org/10.1063/1.532988.

Petitjean, M. (2001) Chiralité quantitative: le modèle des moindres carrés pondérés (in French), Compt. Rend. Acad. Sci. Paris, Sér. IIc, 4(5), 331–333, https://doi.org/10.1016/S1387-1609(01)01241-5. P

etitjean, M. (2002) Chiral mixtures, J. Math. Phys., 43(8), 4147–4157, https://doi.org/10.1063/1.1484559.

Petitjean, M. (2003) Chirality and symmetry measures: a transdisciplinary review, Entropy, 5(3), 271–312, https://doi.org/10.3390/e5030271. Extreme asymmetry and chirality 447

Petitjean, M. (2004) From shape similarity to shape complementarity: toward a docking dheory, J. Math. Chem. 35(3), 147–158, https://doi.org/10.1023/B:JOMC.0000033252.59423.6b.

Petitjean, M. (2006) À propos de la référence achirale (in French), Compt. Rend. Chim., 9(10), 1249–1251, https://doi.org/10.1016/j.crci.2006.03.003.

Petitjean, M. (2007) A definition of symmetry, Symm. Cult. Sci., 18(2-3), 99–119, https://hal.archives-ouvertes.fr/hal-01552499.

Petitjean, M. (2008) About the upper bound of the chiral index of multivariate distributions, AIP Conf. Proc., 1073, 61–66, https://doi.org/10.1063/1.3039023.

Petitjean, M. (2010) Chirality in metric spaces, Symm. Cult. Sci., 21(1–3), 27–36, https://journal-scs.symmetry.hu/issue-content/?volume=21&issue=1-3.

Petitjean, M. (2013) The chiral index: Applications to multivariate distributions and to 3D molecular graphs. Proceedings of the SOR’13 Conference, Dolenjske Toplice, Slovenia, September 25-27, pp. 11–16, https://hal.archives-ouvertes.fr/hal-01952400.

Petitjean, M. (2015) The most Chiral Disphenoid, MATCH Commun. Math. Comput. Chem., 73(2), 375–384, http://match.pmf.kg.ac.rs/content73n2.htm.

Petitjean, M. (2018) Defining and measuring asymmetry, First European Asymmetry Symposium, https://hal.archives-ouvertes.fr/hal-01778387.

Petitjean, M. (2019) About chirality in Minkowski spacetime, Symmetry, 11(10), 1320, https://doi.org/10.3390/sym11101320.

Petitjean, M. (2020a) Chirality of Dirac spinors revisited, Symmetry, 12(4), 616, https://doi.org/10.3390/sym12040616.

Petitjean M. (2020b) Molecular chirality in classical spacetime: solving the controversy about the spinning cone model of rotating molecules, Chem. Eur. J., 26(47), 10648–10652, https://doi.org/10.1002/chem.201904247.

Petitjean, M. (2020c) Chirality in metric spaces. In memoriam Michel Deza, Optim. Lett., 14(2), 329–338, https://doi.org/10.1007/s11590-017-1189-7.

Petitjean, M. (2020d) Comment on "Bad language": Resolving some ambiguities about chirality, Angew. Chem. Int. Ed., 59(20), 7650–7651, https://doi.org/10.1002/anie.201904314.

Petitjean, M. (2020e) Tables of quantiles of the distribution of the empirical chiral index in the case of the uniform law and in the case of the normal law, arXiv:2005.09960 [stat.ME], https://arxiv.org/abs/2005.09960.

Rachev, S.T. (1991) Probability Metrics and the Stability of Stochastic Models, Wiley, New York, Chap. 6. Rachev, S.T., Rüschendorf, L. (1998) Mass Transportation Problems, Springer, New York, Vol. I, Chap. 1, https://doi.org/10.1007/b98893.

Schwartz, A., Petitjean, M. (2008) [6.6]Chiralane: A Remarkably Symmetric Chiral Molecule, Symmetry Cult. Sci., 19(4), 307–316, https://hal.archives-ouvertes.fr/hal-01941526.

ten Berge, J.M.F. (1977) Orthogonal Procrustes rotation for two or more matrices, Psychometrika 42(2), 267–276, https://doi.org/10.1007/BF02294053.

ten Berge, J.M.F. (2006) The rigid orthogonal Procrustes rotation problem, Psychometrika 71(1), 201–205, https://doi.org/10.1007/S11336-004-1160-5

Previous abstract Back to issue content Next abstract